(2E)-4,4-dimethoxy-2-butenal in the synthesis of conjugated dienes and dienals

被引：3

作者：

Badanyan, SO

Makaryan, GM

Ovanesyan, AL

Panosyan, GA

机构：

[1] Armenian Natl Acad Sci, Inst Organ Chem, Yerevan 375091, Armenia

[2] Armenian Natl Acad Sci, Mol Struct Res Ctr, Yerevan, Armenia

来源：

RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2001年 / 37卷 / 05期

关键词：

D O I：

10.1023/A:1012479213224

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Using (2E)-4,4-dimethoxy-2-butenal as starting compound, methods were developed for synthesis of (2E,4E)- and (2E,4Z)-dimethoxyalkadienes. Deacetalization of the latter gives with high yield the corresponding dienals which are naturally occurring compounds and also synthons for preparation of conjugated dienes as key compounds for building up other natural products.

引用

页码：633 / 639

页数：7

共 20 条

[1]

Christmann K. F., 1969, SYNTHESIS-STUTTGART, P38

[2]

EINHORN J, 1984, CR ACAD SCI III-VIE, V299, P773

[3] 3-OXIRANYLPROP-2-ENALS AS SYNTHETIC BUILDING-BLOCKS - EASY AND STEREOSELECTIVE SYNTHESIS OF NATURALLY-OCCURRING (E,Z)-1,3,5-TRIENES AND (E,Z)-2,4-DIENALS, PHEROMONES AND FLAVOR COMPONENTS [J].