Synthesis and structures of [In4(4,4′-bipy)3(HPO4)4(H2PO4)4].4H2O and In4(4,4′-bipy)3(HPO4)4(H2PO4)4, indium phosphates with a pillared layer structure

被引：66

作者：

Lii, KH ^{[1
]}

Huang, YF

机构：

[1] Acad Sinica, Inst Chem, Taipei, Taiwan

[2] Natl Cent Univ, Dept Chem, Chungli 32054, Taiwan

来源：

INORGANIC CHEMISTRY | 1999年 / 38卷 / 06期

关键词：

D O I：

10.1021/ic9715106

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An indium phosphate, [In-4(4,4'-bipy)(3)(HPO4)(4)(H-2-PO4)(4)] . 4H(2)O, prepared as single crystals under solvo-thermal conditions, has a new structure which consists of neutral sheets of indium phosphate linked through 4,4'-bipyridine pillars to generate channels in which water molecules reside. The structure of the anhydrous compound, In-4(4,4'-bipy)(3)(HPO4)(4)(H2PO4)(4), is also determined.

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页码：1348 / +

页数：4

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