Hydrogen-bonded complexes of oxetanes and other ethers with nitric acid and with trifluoroacetic acid in [H-2]trichloromethane

被引：5

作者：

Hylands, KA ^{[1
]}

Moodie, RB ^{[1
]}

机构：

[1] UNIV EXETER,DEPT CHEM,EXETER EX4 4QD,DEVON,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1996年 / 10期

关键词：

D O I：

10.1039/p29960002073

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Equilibrium constants for hydrogen-bonded complexation of nitric acid and trifluoroacetic acid with 3,3-pentamethyleneoxetane, oxetane, 3-phenyloxetane, tetrahydrofuran, butyl methyl ether 3-(4-nitrophenyl)oxetane and dibenzyl ether, measured by H-1 NMR spectroscopy, are reported. Reasons for the signal broadening observed with the more strongly basic ethers with nitric acid but not with trifluoroacetic acid are discussed.

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页码：2073 / 2077

页数：5

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