Nanoparticles of zinc compounds obtained by thermooxidative degradation

被引：8

作者：

Dumbrava, A

Jurca, B

Ciupina, V

Segal, E

Brezeanu, M

机构：

[1] Ovidius Univ, Fac Phys & Chem, Dept Chem, Constanta, Romania

[2] Univ Bucharest, Fac Chem, Dept Chem Phys, Bucharest, Romania

[3] Ovidius Univ, Fac Phys & Chem, Dept Phys, Constanta, Romania

[4] Univ Bucharest, Fac Chem, Dept Inorgan Chem, Bucharest, Romania

来源：

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2005年 / 79卷 / 03期

关键词：

complex compounds; nanoparticles; phenantroline; TEM; thermal analysis; thermooxidative degradation; thiosulfate; zinc;

D O I：

10.1007/s10973-005-0570-4

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Nanocrystalline zinc compounds were obtained by thermooxidative degradation of zinc complexes. There are presented the conditions of synthesis and results in the characterisation (chemical analysis, thermal analysis) for two complex compounds of zinc: [Zn(phen)(S2O3)(H2O)] center dot 2H(2)O and [Zn(phen) 2(H2O)(2)][Zn(phen)(S2O3)(2)] center dot 4H(2)O. On the basis of transmission electron microscopy (TEM) the complex sulfide and zinc oxide (prepared by controlled thermal decomposition of these compounds) may be included in the nanomaterials category.

引用

页码：509 / 514

页数：6

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