Fluorescent anion receptors with iminoylthiourea binding sites -: Selective hydrogen bond mediated recognition of CO32-,HCO3- and HPO42-

被引：90

作者：

Hennrich, G

Sonnenschein, H

Resch-Genger, U

机构：

[1] BAM, Fed Inst Mat Res & Testing, D-12489 Berlin, Germany

[2] Inst Nonclass Chem, D-04303 Leipzig, Germany

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 15期

关键词：

D O I：

10.1016/S0040-4039(01)00324-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A number of structurally simple, fluorescent sensor molecules based on the iminoylthiourea/1,2,4-thiadiazole unit are presented, which display extraordinarily strong fluorescence enhancement selectively upon complexation of HCO3-, CO32- and HPO42-. (C) 2001 Elsevier Science Ltd. All rights reserved.

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页码：2805 / 2808

页数：4

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共 29 条

[1] A preorganized macrocycle based on a bicyclic guanidinium subunit with six convergent hydrogen bonds for anion recognition [J].

Alcázar, V ;

Segura, M ;

Prados, P ;

de Mendoza, J .

TETRAHEDRON LETTERS, 1998, 39 (09) :1033-1036

[2] Transition-metal receptor systems for the selective recognition and sensing of anionic guest species [J].

Beer, PD .

ACCOUNTS OF CHEMICAL RESEARCH, 1998, 31 (02) :71-80

[3] Zwitterionic guanidinium compounds serve as electroneutral anion hosts [J].

Berger, M ;

Schmidtchen, FP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (43) :9986-9993

[4] Strong hydrogen bond-mediated complexation of H2PO4- by neutral bis-thiourea hosts [J].

Buhlmann, P ;

Nishizawa, S ;

Xiao, KP ;

Umezawa, Y .

TETRAHEDRON, 1997, 53 (05) :1647-1654

[5] CHEMICAL COMMUNICATION IN WATER USING FLUORESCENT CHEMOSENSORS [J].

CZARNIK, AW .

ACCOUNTS OF CHEMICAL RESEARCH, 1994, 27 (10) :302-308

[6] Anion recognition by tripodal receptors derived from cholic acid [J].

Davis, AP ;

Perry, JJ ;

Williams, RP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (07) :1793-1794

[7] Signaling recognition events with fluorescent sensors and switches [J].

de Silva, AP ;

Gunaratne, HQN ;

Gunnlaugsson, T ;

Huxley, AJM ;

McCoy, CP ;

Rademacher, JT ;

Rice, TE .

CHEMICAL REVIEWS, 1997, 97 (05) :1515-1566

[8] MOLECULAR RECOGNITION - BIS-ACYLGUANIDINIUMS PROVIDE A SIMPLE FAMILY OF RECEPTORS FOR PHOSPHODIESTERS [J].

DIXON, RP ;

GEIB, SJ ;

HAMILTON, AD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (01) :365-366

[9] The design of luminescent sensors for anions and ionisable analytes [J].

Fabbrizzi, L ;

Licchelli, M ;

Rabaioli, G ;

Taglietti, A .

COORDINATION CHEMISTRY REVIEWS, 2000, 205 :85-108

[10] A STUDY OF THE PHASE-TRANSFER ALKOXYCARBONYLATION OF SECONDARY ALKYL AMINES - APPLICATION OF A FACTORIAL DESIGN [J].

GOMEZPARRA, V ;

SANCHEZ, F ;

TORRES, T .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1987, (06) :695-697