Strongly coverage-dependent excitations of adsorbed molecular hydrogen

被引:59
作者
Gupta, JA [1 ]
Lutz, CP [1 ]
Heinrich, AJ [1 ]
Eigler, DM [1 ]
机构
[1] IBM Corp, Almaden Res Ctr, Div Res, San Jose, CA 95120 USA
来源
PHYSICAL REVIEW B | 2005年 / 71卷 / 11期
关键词
D O I
10.1103/PhysRevB.71.115416
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We have observed prominent nonlinearities in differential conductance spectra of H-2 on copper surfaces using a low-temperature scanning tunneling microscope. These nonlinearities result from transitions between states of H-2 with distinct conductances. Tunneling electrons drive these transitions by giving up energy to highly coverage-dependent excitations that do not correspond to known vibrational or rotational modes of H-2. The nonlinear conductance features can be modeled by extending the conventional framework for inelastic electron tunneling spectroscopy to include saturation effects.
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页数:5
相关论文
共 15 条
[1]   EFFECT OF VIBRATIONAL AND ROTATIONAL EXCITATION ON DISSOCIATIVE ATTACHMENT IN HYDROGEN [J].
ALLAN, M ;
WONG, SF .
PHYSICAL REVIEW LETTERS, 1978, 41 (26) :1791-1794
[2]   OBSERVATION OF ROTATIONAL TRANSITIONS FOR H-2, D2, AND HD ADSORBED ON CU(100) [J].
ANDERSSON, S ;
HARRIS, J .
PHYSICAL REVIEW LETTERS, 1982, 48 (08) :545-548
[3]   OBSERVATION OF ROTATIONAL EXCITATIONS OF H-2 ADSORBED ON AG SURFACES [J].
AVOURIS, P ;
SCHMEISSER, D ;
DEMUTH, JE .
PHYSICAL REVIEW LETTERS, 1982, 48 (03) :199-202
[4]   H2 adsorbed in a two-dimensional quantum rotor state on a stepped copper surface [J].
Bengtsson, L ;
Svensson, K ;
Hassel, M ;
Bellman, J ;
Persson, M ;
Andersson, S .
PHYSICAL REVIEW B, 2000, 61 (24) :16921-16932
[5]   Vibrationally mediated negative differential resistance in a single molecule [J].
Gaudioso, J ;
Lauhon, LJ ;
Ho, W .
PHYSICAL REVIEW LETTERS, 2000, 85 (09) :1918-1921
[6]   Two-dimensional H2 clusters:: A path-integral Monte Carlo study -: art. no. 174527 [J].
Gordillo, MC ;
Ceperley, DM .
PHYSICAL REVIEW B, 2002, 65 (17) :1-4
[7]   Superfluidity in H-2 films [J].
Gordillo, MC ;
Ceperley, DM .
PHYSICAL REVIEW LETTERS, 1997, 79 (16) :3010-3013
[8]   Evidence for superfluidity in para-hydrogen clusters inside helium-4 droplets at 0.15 kelvin [J].
Grebenev, S ;
Sartakov, B ;
Toennies, JP ;
Vilesov, AF .
SCIENCE, 2000, 289 (5484) :1532-1535
[9]  
LONDON F, 1964, SUPERFLUIDS, V2, P33
[10]   ADSORPTION AND DISSOCIATION OF H-2 ON MG SURFACES [J].
NORSKOV, JK ;
HOUMOLLER, A ;
JOHANSSON, PK ;
LUNDQVIST, BI .
PHYSICAL REVIEW LETTERS, 1981, 46 (04) :257-260