Expandable graphite/polyamide-6 nanocomposites

被引:135
作者
Uhl, FM
Yao, Q
Nakajima, H
Manias, E
Wilkie, CA
机构
[1] Marquette Univ, Dept Chem, Milwaukee, WI 53201 USA
[2] Polytech Univ, Dept Chem Engn, Brooklyn, NY 11201 USA
[3] Penn State Univ, Dept Mat Sci & Engn, University Pk, PA 16802 USA
关键词
expandable grapline; polyamide-6; nanocomposites;
D O I
10.1016/j.polymdegradstab.2005.01.004
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Polyamide-6 (PA-6)/graphite nanocomposites were prepared by melt blending, using a variety of graphites, including virgin graphite, expandable graphites and expanded graphite. The resulting nanocomposites were characterized by X-ray diffraction, thermogravimetric analysis, cone calorimetry, and tensile mechanical analysis. Nanocomposite formation does occur, as denoted by the nanometrc dispersion of graphite layers in the polymer matrix, and the dispersion depends on the graphite treatment. The material properties of the resulting composites are improved relative to the virgin/unfilled polymer; in particular, there is an enhancement of the thermal stability without any significant deterioration of the mechanical properties. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码:70 / 84
页数:15
相关论文
共 58 条
[1]   Polymer-layered silicate nanocomposites: Preparation, properties and uses of a new class of materials [J].
Alexandre, Michael ;
Dubois, Philippe .
Materials Science and Engineering: R: Reports, 2000, 28 (1-2) :1-63
[2]   Modeling the phase behavior of polymer/clay nanocomposites [J].
Balazs, AC ;
Singh, C ;
Zhulina, E ;
Lyatskaya, Y .
ACCOUNTS OF CHEMICAL RESEARCH, 1999, 32 (08) :651-657
[3]   Modeling the interactions between polymers and clay surfaces through self-consistent field theory [J].
Balazs, AC ;
Singh, C ;
Zhulina, E .
MACROMOLECULES, 1998, 31 (23) :8370-8381
[4]  
Camino G., 2001, FIRES POLYM MAT SOLU, P90
[5]   Preparation of polystyrene-graphite conducting nanocomposites via intercalation polymerization [J].
Chen, GH ;
Wu, DJ ;
Weng, WG ;
He, B ;
Yan, WI .
POLYMER INTERNATIONAL, 2001, 50 (09) :980-985
[6]   Nonlinear conduction in nylon-6/foliated graphite nanocomposites above the percolation threshold [J].
Chen, GH ;
Weng, WG ;
Wu, DJ ;
Wu, CL .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2004, 42 (01) :155-167
[7]   Nylon 6 nanocomposites by melt compounding [J].
Cho, JW ;
Paul, DR .
POLYMER, 2001, 42 (03) :1083-1094
[8]   Polymer-clay nanocomposites: exfoliation of organophilic montmorillonite nanolayers in polystyrene [J].
Fu, X ;
Qutubuddin, S .
POLYMER, 2001, 42 (02) :807-813
[9]  
Giannelis EP, 1999, ADV POLYM SCI, V138, P107
[10]  
Gilman J.W., 1998, FIRE RETARDANCY POLY, P201