Reversible carboxylation of N-heterocyclic carbenes

被引：274

作者：

Duong, HA ^{[1
]}

Tekavec, TN ^{[1
]}

Arif, AM ^{[1
]}

Louie, J ^{[1
]}

机构：

[1] Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 01期

关键词：

D O I：

10.1039/b311350g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Spectroscopic analysis, thermogravimetric analysis, and crossover experiments performed on a series of imidazolium carboxylates revealed carboxylation was reversible with N-aryl substituted adducts.

引用

页码：112 / 113

页数：2

共 16 条

[1] A STABLE CRYSTALLINE CARBENE
ARDUENGO, AJ
HARLOW, RL
KLINE, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (01) : 361 - 363
[2] First example of N-heterocyclic carbenes as catalysts for living polymerization:: Organocatalytic ring-opening polymerization of cyclic esters
Connor, EF
Nyce, GW
Myers, M
Möck, A
Hedrick, JL
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (06) : 914 - 915
[3] Connors K. A, 1987, BINDING CONSTANTS ME
[4] Efficient transesterification/acylation reactions mediated by N-heterocyclic carbene catalysts
Grasa, GA
Güveli, T
Singh, R
Nolan, SP
[J]. JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (07) : 2812 - 2819
[5] N-heterocyclic carbenes as versatile nucleophilic catalysts for transesterification/acylation reactions
Grasa, GA
Kissling, RM
Nolan, SP
[J]. ORGANIC LETTERS, 2002, 4 (21) : 3583 - 3586
[6] Herrmann WA, 2001, ADV ORGANOMET CHEM, V48, P1
[7] 1,3-dimethylimidazolium-2-carboxylate:: the unexpected synthesis of an ionic liquid precursor and carbene-CO2 adduct
Holbrey, JD
Reichert, WM
Tkatchenko, I
Bouajila, E
Walter, O
Tommasi, I
Rogers, RD
[J]. CHEMICAL COMMUNICATIONS, 2003, (01) : 28 - 29
[8] KUHN N, 1993, SYNTHESIS-STUTTGART, P561
[9] Kuhn N, 1999, Z NATURFORSCH B, V54, P427
[10] Phase-separable catalysis using room temperature ionic liquids and supercritical carbon dioxide
Liu, FC
Abrams, MB
Baker, RT
Tumas, W
[J]. CHEMICAL COMMUNICATIONS, 2001, (05) : 433 - 434

← 1 2 →