Polyamidoamine dendrimers prepared inside the channels of pore-expanded periodic mesoporous silica

被引：82

作者：

Reynhardt, JPK ^{[1
]}

Yang, Y ^{[1
]}

Sayari, A ^{[1
]}

Alper, H ^{[1
]}

机构：

[1] Univ Ottawa, CCRI, Dept Chem, Ottawa, ON K1N 6N5, Canada

来源：

ADVANCED FUNCTIONAL MATERIALS | 2005年 / 15卷 / 10期

关键词：

D O I：

10.1002/adfm.200400622

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Polyamidoamine dendrimers up to the fourth generation have been grown with unprecedentedly high loading within the channels of pore-expanded (10.6 nm) MCM-41 silica. In-depth characterization using nitrogen adsorption, solid-state NMR, FTIR, thermogravimetry, and elemental analysis showed that the dendrimers grow inside the channels with an average yield better than 99 %. The pore size and structure of the support have been found to be determining factors as to how much dendrimer growth can be achieved.

引用

页码：1641 / 1646

页数：6

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