Ring-Opening Reactions within Porous Metal-Organic Frameworks

被引：117

作者：

Britt, David ^{[1
]}

Lee, Chain ^{[1
]}

Uribe-Romo, Fernando J. ^{[1
]}

Furukawa, Hiroyasu ^{[1
]}

Yaghi, Omar M. ^{[1
]}

机构：

[1] Univ Calif Los Angeles, Ctr Reticular Chem, Calif NanoSyst Inst, Dept Chem & Biochem, Los Angeles, CA 90095 USA

来源：

INORGANIC CHEMISTRY | 2010年 / 49卷 / 14期

关键词：

DESIGN; FUNCTIONALIZATION; SEPARATION; MOFS; CO2;

D O I：

10.1021/ic100652x

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new metal organic framework (MOF) structures, IRMOF-3b and -3c, were prepared by ring-opening reaction of 1,3-propane-sultone and 2-methylaziridine with an amine functionalized MOF, IRMOF-3. The new structures are permanently functionalized with covalently linked sulfonate and alkyamine units, respectively. The underlying framework structure is retained after reaction as confirmed by powder X-ray diffraction. The high porosity of IRMOF-3 is also maintained, as evidenced by nitrogen adsorption experiments, which yield Brunauer-Emmett-Teller (BET) surface areas of 1380 and 530 m(2) g(-1) compared to 2040 m(2) g(-1) in the parent material. Ring-opening reactions provide a versatile route to irreversible binding of a range of functionalities that are otherwise difficult to access in MOFs.

引用

页码：6387 / 6389

页数：3

共 12 条

[1] An Amine-Functionalized MIL-53 Metal-Organic Framework with Large Separation Power for CO2 and CH4 [J].

Couck, Sarah ;

Denayer, Joeri F. M. ;

Baron, Gino V. ;

Remy, Tom ;

Gascon, Jorge ;

Kapteijn, Freek .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (18) :6326-+

[2] Strong CO2 Binding in a Water-Stable, Triazolate-Bridged Metal-Organic Framework Functionalized with Ethylenediamine [J].

Demessence, Aude ;

D'Alessandro, Deanna M. ;

Foo, Maw Lin ;

Long, Jeffrey R. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (25) :8784-+

[3] Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage [J].

Eddaoudi, M ;

Kim, J ;

Rosi, N ;

Vodak, D ;

Wachter, J ;

O'Keeffe, M ;

Yaghi, OM .

SCIENCE, 2002, 295 (5554) :469-472

[4] Modular chemistry: Secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks [J].

Eddaoudi, M ;

Moler, DB ;

Li, HL ;

Chen, BL ;

Reineke, TM ;

O'Keeffe, M ;

Yaghi, OM .

ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (04) :319-330

[5] Postsynthetic Modification: A Versatile Approach Toward Multifunctional Metal-Organic Frameworks [J].

Garibay, Sergio J. ;

Wang, Zhenqiang ;

Tanabe, Kristine K. ;

Cohen, Seth M. .

INORGANIC CHEMISTRY, 2009, 48 (15) :7341-7349

[6] Coordination pillared-layer type compounds having pore surface functionalization by anionic sulfonate groups [J].

Horike, Satoshi ;

Bureekaew, Sareeya ;

Kitagawa, Susumu .

CHEMICAL COMMUNICATIONS, 2008, (04) :471-473

[7]

Hurd JA, 2009, NAT CHEM, V1, P705, DOI [10.1038/NCHEM.402, 10.1038/nchem.402]

[8] Amine grafting on coordinatively unsaturated metal centers of MOFs:: Consequences for catalysis and metal encapsulation [J].

Hwang, Young Kyu ;

Hong, Do-Young ;

Chang, Jong-San ;

Jhung, Sung Hwa ;

Seo, You-Kyong ;

Kim, Jinheung ;

Vimont, Alexandre ;

Daturi, Marco ;

Serre, Christian ;

Ferey, Gerard .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (22) :4144-4148

[9] Crystals as molecules: Postsynthesis covalent functionalization of zeolitic imidazolate frameworks [J].

Morris, William ;

Doonan, Christian J. ;

Furukawa, Hiroyasu ;

Banerjee, Rahul ;

Yaghi, Omar M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (38) :12626-+

[10] A homochiral metal-organic porous material for enantioselective separation and catalysis [J].

Seo, JS ;

Whang, D ;

Lee, H ;

Jun, SI ;

Oh, J ;

Jeon, YJ ;

Kim, K .

NATURE, 2000, 404 (6781) :982-986

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