Cyano-substituted model compounds and conjugated polymers of PPV

被引:10
作者
de Souza, MM
Rumbles, G [1 ]
Russell, DL
Samuel, IDW
Moratti, SC
Holmes, AB
Burn, PL
机构
[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England
[2] Univ Durham, Dept Phys, Durham DH1 3LE, England
[3] Melville Lab Polymer Synthesis, Cambridge CB2 1EW, England
[4] Dyson Perrins Lab, Oxford OX1 3QY, England
关键词
photoluminescence; UV-Vis absorption; polyphenylenevinylene and derivatives;
D O I
10.1016/S0379-6779(00)00890-0
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We present an experimental characterisation of cyano-substituted p-phenylene vinylene model compounds and polymers. The photophysics of these samples in toluene solution are investigated using steady state and time-resolved photoluminescence spectroscopy The influence of cyano and methoxy substitution on the energetics and the natural radiative lifetime are studied.
引用
收藏
页码:635 / 636
页数:2
相关论文
共 9 条
[1]   ELECTRONIC-STRUCTURE OF PHENYLENE VINYLENE OLIGOMERS - INFLUENCE OF DONOR-ACCEPTOR SUBSTITUTIONS [J].
CORNIL, J ;
DOSSANTOS, DA ;
BELJONNE, D ;
BREDAS, JL .
JOURNAL OF PHYSICAL CHEMISTRY, 1995, 99 (15) :5604-5611
[2]   Electroluminescence in conjugated polymers [J].
Friend, RH ;
Gymer, RW ;
Holmes, AB ;
Burroughes, JH ;
Marks, RN ;
Taliani, C ;
Bradley, DDC ;
Dos Santos, DA ;
Brédas, JL ;
Lögdlund, M ;
Salaneck, WR .
NATURE, 1999, 397 (6715) :121-128
[3]   EFFICIENT LIGHT-EMITTING-DIODES BASED ON POLYMERS WITH HIGH ELECTRON-AFFINITIES [J].
GREENHAM, NC ;
MORATTI, SC ;
BRADLEY, DDC ;
FRIEND, RH ;
HOLMES, AB .
NATURE, 1993, 365 (6447) :628-630
[4]   Synthesis and structural studies of poly(p-phenylenevinylene) analogous model compounds [J].
Hohloch, M ;
Maichle-Mossmer, C ;
Hanack, M .
CHEMISTRY OF MATERIALS, 1998, 10 (05) :1327-1332
[5]   A study on the molecular weight of the chloro-precursor polymer to MEHPPV [J].
McCallien, DWJ ;
Thomas, AC ;
Burn, PL .
JOURNAL OF MATERIALS CHEMISTRY, 1999, 9 (04) :847-849
[6]   HIGH ELECTRON-AFFINITY POLYMERS FOR LEDS [J].
MORATTI, SC ;
CERVINI, R ;
HOLMES, AB ;
BAIGENT, DR ;
FRIEND, RH ;
GREENHAM, NC ;
GRUNER, J ;
HAMER, PJ .
SYNTHETIC METALS, 1995, 71 (1-3) :2117-2120
[7]  
OCONNER DV, 1984, TIME CORRELATED SING
[8]   Tuning of fluorescence in films and nanoparticles of oligophenylenevinylenes [J].
Oelkrug, D ;
Tompert, A ;
Gierschner, J ;
Egelhaaf, HJ ;
Hanack, M ;
Hohloch, M ;
Steinhuber, E .
JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (11) :1902-1907
[9]   Origin of line broadening in the electronic absorption spectra of conjugated polymers: Three-pulse-echo studies of MEH-PPV in toluene [J].
Scholes, GD ;
Larsen, DS ;
Fleming, GR ;
Rumbles, G ;
Burn, PL .
PHYSICAL REVIEW B, 2000, 61 (20) :13670-13678