Dynamics study of the OH+O2 branching atmospheric reaction.: 2.: Influence of reactants internal energy in HO2 and O3 formation

被引：22

作者：

Caridade, PJSB

Zhang, L

Garrido, JD

Varandas, AJC ^{[1
]}

机构：

[1] Univ Coimbra, Dept Quim, P-3049 Coimbra, Portugal

[2] Inst Super Ciencias & Tecnol Nucl, Dept Fis Gen & Matemat, La Havana 6163, Cuba

来源：

JOURNAL OF PHYSICAL CHEMISTRY A | 2001年 / 105卷 / 18期

关键词：

D O I：

10.1021/jp004308o

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The effect of reactants vibrational and rotational excitation on products (HO2 + O and O-3 + H) formation is investigated for the title reaction by using the quasiclassical trajectory method and the realistic double many-body expansion (DMBE) potential energy surface for ground-state HO3. It is shown that it can be a potential source of ozone in the upper atmosphere.

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收藏

页码：4395 / 4402

页数：8

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