The role of ordered block copolymer morphology in the performance of organic/inorganic photovoltaic devices

被引：16

作者：

Gratt, JA

Cohen, RE

机构：

[1] MIT, Dept Mat Sci & Engn, Cambridge, MA 02139 USA

[2] MIT, Program Polymer Sci & Technol, Cambridge, MA 02139 USA

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 2004年 / 91卷 / 05期

关键词：

block copolymers; photoroltaics;

D O I：

10.1002/app.13526

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A triblock copolymer consisting of hole-transport, electron-transport, and nanocluster-binding moieties was used in the fabrication of photovoltaic test devices. Depending on the casting solvent used in the device fabrication process, the morphology of the block copolymer in the devices was either an ordered, perpendicular cylindrical phase or a uniformly mixed homogeneous material. The photovoltaic action spectra of these two device types revealed clearly that the charge collection efficiency was influenced favorably by the microphase separation of the ordered system. Underlying mechanisms for these observations are discussed. (C) 2004 Wiley Periodicals, Inc.

引用

收藏

页码：3362 / 3368

页数：7

相关论文

共 30 条

[1] New triarylamine-containing polymers as hole transport materials in organic light-emitting diodes: Effect of polymer structure and cross-linking on device characteristics [J].

Bellmann, E ;

Shaheen, SE ;

Thayumanavan, S ;

Barlow, S ;

Grubbs, RH ;

Marder, SR ;

Kippelen, B ;

Peyghambarian, N .

CHEMISTRY OF MATERIALS, 1998, 10 (06) :1668-1676

[2] Cavitated block copolymer micellar thin films: Lateral arrays of open nanoreactors [J].

Boontongkong, Y ;

Cohen, RE .

MACROMOLECULES, 2002, 35 (09) :3647-3652

[3] Electroluminescence from new polynorbornenes that contain blue-light-emitting and charge-transport side chains [J].

Boyd, TJ ;

Geerts, Y ;

Lee, JK ;

Fogg, DE ;

Lavoie, GG ;

Schrock, RR ;

Rubner, MF .

MACROMOLECULES, 1997, 30 (12) :3553-3559

[4] VISIBLE-LIGHT EMISSION FROM SEMICONDUCTING POLYMER DIODES [J].

BRAUN, D ;

HEEGER, AJ .

APPLIED PHYSICS LETTERS, 1991, 58 (18) :1982-1984

[5] POLY(P-PHENYLENEVINYLENE) LIGHT-EMITTING-DIODES - ENHANCED ELECTROLUMINESCENT EFFICIENCY THROUGH CHARGE CARRIER CONFINEMENT [J].

BROWN, AR ;

BRADLEY, DDC ;

BURROUGHES, JH ;

FRIEND, RH ;

GREENHAM, NC ;

BURN, PL ;

HOLMES, AB ;

KRAFT, A .

APPLIED PHYSICS LETTERS, 1992, 61 (23) :2793-2795

[6] NON-EQUILIBRIUM MORPHOLOGIES OF A DIBLOCK CO-POLYMER OF POLYISOPRENE AND POLY(NORMAL-BUTYL METHACRYLATE) [J].

COHEN, RE ;

BATES, FS .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1980, 18 (10) :2143-2148

[7] PATH-DEPENDENT MORPHOLOGIES OF A DIBLOCK COPOLYMER OF POLYSTYRENE HYDROGENATED POLYBUTADIENE [J].

COHEN, RE ;

CHENG, PL ;

DOUZINAS, K ;

KOFINAS, P ;

BERNEY, CV .

MACROMOLECULES, 1990, 23 (01) :324-327

[8] ELECTROLUMINESCENCE FROM CDSE QUANTUM-DOT POLYMER COMPOSITES [J].

DABBOUSI, BO ;

BAWENDI, MG ;

ONITSUKA, O ;

RUBNER, MF .

APPLIED PHYSICS LETTERS, 1995, 66 (11) :1316-1318

[9] Supramolecular self-assembly and opto-electronic properties of semiconducting block copolymers [J].

de Boer, B ;

Stalmach, U ;

van Hutten, PF ;

Melzer, C ;

Krasnikov, VV ;

Hadziioannou, G .

POLYMER, 2001, 42 (21) :9097-9109

[10] Poly(p-pyridine)- and poly(p-pyridyl vinylene)-based polymers: Their photophysics and application to SCALE devices [J].

Epstein, AJ ;

Blatchford, JW ;

Wang, YZ ;

Jessen, SW ;

Gebler, DD ;

Lin, LB ;

Gustafson, TL ;

Wang, HL ;

Park, YW ;

Swager, TM ;

MacDiarmid, AG .

SYNTHETIC METALS, 1996, 78 (03) :253-261