Redox-induced kappa(2)-kappa(3) isomerisation in rhodium hydrotris(3,5-dimethylpyrazolyl)borate chemistry: The stabilisation of square-pyramidal rhodium(II)

被引：45

作者：

Connelly, NG

Emslie, DJH

Metz, B

Orpen, AG

Quayle, MJ

机构：

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 19期

关键词：

D O I：

10.1039/cc9960002289

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

One-electron. oxidation of the square-planar, 16-electron complex [Rh(CO)(PPh(3)>(kappa(2)-Tp')] with [FeCp(2)][PF6] gives the square-pyramidal Rh-II complex [Rh(CO)(PPh(3))(kappa(3)-Tp')][PF6] in which the third pyrazolyl group of Tp' is N-bound in the axial position by a three-electron two-centrebond (Rh-N-axial 0.13 Angstrom longer than Rh-N-basal).

引用

页码：2289 / 2290

页数：2

共 11 条

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