Hydrodemethoxylation, hydrodechloration, hydrodesulfurization, and hydrodeamination of neutral (eta(5)-X-substituted-cyclohexadienyl)tricarbonylmanganese complexes (X=OMe, Cl, SPh, NEt(2)) upon treatment with hydride and then acid: cine and tele nucleophilic substitutions

被引：42

作者：

Balssa, F ^{[1
]}

Gagliardini, V ^{[1
]}

RoseMunch, F ^{[1
]}

Rose, E ^{[1
]}

机构：

[1] UNIV PARIS 06,LAB SYNTH ORGAN & ORGANOMET,CNRS,URA 408,F-75252 PARIS 05,FRANCE

来源：

ORGANOMETALLICS | 1996年 / 15卷 / 21期

关键词：

D O I：

10.1021/om960621u

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of (eta(5)-X-substituted-cyclohexadienyl)tricarbonylmanganese complexes (X = alkoxy, halogeno, dimethylamino and thio) with hydrides and a proton source gave eta(5)-cyclohexadienyl complexes resulting from a cleavage of the C-O, C-Cl, C-N and C-S bonds: The eta(3)-substituted cyclohexenyl intermediates underwent elimination of an agostic hydrogen and the alkoxy, halogeno, amino, or thio group.

引用

页码：4373 / 4382

页数：10

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