Recent advances in Sonogashira reactions

被引：1374

作者：

Chinchilla, Rafael ^{[1
]}

Najera, Carmen

机构：

[1] Univ Alicante, Fac Ciencias, Dept Quim Organ, Alicante 03080, Spain

来源：

CHEMICAL SOCIETY REVIEWS | 2011年 / 40卷 / 10期

关键词：

CROSS-COUPLING REACTIONS; PD-CATALYZED SONOGASHIRA; ONE-POT SYNTHESIS; PALLADIUM(II) ETHYLENEDIAMINE COMPLEX; IRON/COPPER COCATALYZED ALKYNYLATION; SUPPORTED METAL NANOPARTICLES; NONLINEAR-OPTICAL-PROPERTIES; MIXED AQUEOUS-MEDIUM; 1ST TOTAL-SYNTHESIS; COPPER-FREE;

D O I：

10.1039/c1cs15071e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The coupling of aryl or vinyl halides with terminal acetylenes catalysed by palladium and other transition metals, commonly termed as Sonogashira cross-coupling reaction, is one of the most important and widely used sp(2)-sp carbon-carbon bond formation reactions in organic synthesis, frequently employed in the synthesis of natural products, biologically active molecules, heterocycles, molecular electronics, dendrimers and conjugated polymers or nanostructures. This critical review focuses on developments in the Sonogashira reaction achieved in recent years concerning catalysts, reaction conditions and substrates (352 references).

引用

页码：5084 / 5121

页数：38

共 434 条

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