2-Arylallyl as a new protecting group for amines, amides and alcohols

被引：25

作者：

Barluenga, J

Fañanás, FJ

Sanz, R

Marcos, C

Ignacio, JM

机构：

[1] Univ Oviedo, Unidad Asociada CSIC, Inst Univ Quim Organomet Enrique Moles, E-33006 Oviedo, Spain

[2] Univ Burgos, Fac Ciencias, Dept Quim, Area Quim Organ, Burgos 09001, Spain

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 07期

关键词：

D O I：

10.1039/b414966a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Amines, amides and ethers containing 2-arylallyl groups are selectively and easily deprotected with tert-butyllithium. This transformation probably involves a carbolithiation reaction of the styrenyl moiety followed by a beta-elimination process.

引用

页码：933 / 935

页数：3

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