Synthesis of 2-functionalized allyl tris(trimethylsilyl)silanes

被引：29

作者：

Chatgilialoglu, C ^{[1
]}

Ballestri, M ^{[1
]}

Vecchi, D ^{[1
]}

Curran, DP ^{[1
]}

机构：

[1] UNIV PITTSBURGH,DEPT CHEM,PITTSBURGH,PA 15260

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 35期

基金：

美国国家科学基金会; 美国国家卫生研究院;

关键词：

D O I：

10.1016/0040-4039(96)01353-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reactions of unsubstituted and 2-substituted allyl phenyl sulfides with tris(trimethylsilyl)silane provide the corresponding allyl tris(trimethylsilyl)silanes rapidly and in high yields while the related reactions with allyl phenyl sulfones occur more slowly and in moderate yields. Copyright (C) 1996 Elsevier Science Ltd

引用

收藏

页码：6383 / 6386

页数：4

相关论文

共 26 条

[1] REACTIONS OF A GLYCIDYL RADICAL EQUIVALENT WITH 2-FUNCTIONALIZED ALLYL STANNANES [J].

BALDWIN, JE ;

ADLINGTON, RM ;

LOWE, C ;

ONEIL, IA ;

SANDERS, GL ;

SCHOFIELD, CJ ;

SWEENEY, JB .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (15) :1030-1031

[2] RADICAL REACTIONS IN SYNTHESIS - CARBON CARBON BOND FORMATION FROM 2-SUBSTITUTED ALLYL TRIALKYL STANNANES [J].

BALDWIN, JE ;

ADLINGTON, RM ;

BIRCH, DJ ;

CRAWFORD, JA ;

SWEENEY, JB .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (17) :1339-1340

[3]

BRAVERMAN S, 1988, CHEM SULPHONES SULPH, P665

[4] (Z)-(E) INTERCONVERSION OF OLEFINS BY THE ADDITION-ELIMINATION SEQUENCE OF THE (TMS)(3)SI. RADICAL [J].

CHATGILIALOGLU, C ;

BALLESTRI, M ;

FERRERI, C ;

VECCHI, D .

JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (12) :3826-3831

[5] STRUCTURAL AND CHEMICAL-PROPERTIES OF SILYL RADICALS [J].

CHATGILIALOGLU, C .

CHEMICAL REVIEWS, 1995, 95 (05) :1229-1251

[6] ORGANOSILANES AS RADICAL-BASED REDUCING AGENTS IN SYNTHESIS [J].

CHATGILIALOGLU, C .

ACCOUNTS OF CHEMICAL RESEARCH, 1992, 25 (04) :188-194

[7] PROGRESS OF THE BARTON-MCCOMBIE METHODOLOGY - FROM TIN HYDRIDES TO SILANES [J].

CHATGILIALOGLU, C ;

FERRERI, C .

RESEARCH ON CHEMICAL INTERMEDIATES, 1993, 19 (08) :755-775

[8] ELECTRON-SPIN RESONANCE STUDIES .57. ALKANE-SULFINATE AND ARENE-SULFINATE ESTERS - INVESTIGATION OF THEIR PHOTO-CHEMICAL DECOMPOSITION AND REACTIONS WITH THE TERT-BUTOXYL RADICAL [J].

CHATGILIALOGLU, C ;

GILBERT, BC ;

KIRK, CM ;

NORMAN, ROC .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1979, (08) :1084-1092

[9]

Chatgilialoglu C., 1988, CHEM SULFONES SULFOX, P1081

[10]

Chatgilialoglu C., 1993, CHEM SULFUR CONTAINI, P363