Allylgallation of cyclopropenes. Crystal structure of a novel cyclopropylgallium compound prepared by allylgallation of hydroxy-bearing cyclopropene

被引：13

作者：

Araki, S

Tanaka, T

Hirashita, T

Setsune, J

机构：

[1] Nagoya Inst Technol, Grad Sch Engn, Omohi Coll, Showa Ku, Nagoya, Aichi 4668555, Japan

[2] Kobe Univ, Fac Sci, Dept Chem, Kobe, Hyogo 6578501, Japan

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 43期

关键词：

allyation; carbometallation; cyclopropanes; cyclopropenes; gallium and compounds;

D O I：

10.1016/j.tetlet.2003.08.121

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Allylgallation of cyclopropenes with allylgallium sesquibromide has been investigated a novel cyclopropylgallium compound was isolated via allylgallation of hydroxy-bearing cyclopropene, and its structure was fully characterized by X-ray crystallography. (C) 2003 Elsevier Ltd. All rights reserved.

引用

页码：8001 / 8003

页数：3

共 19 条

[1] Araki S, 2001, CHEM-EUR J, V7, P2784, DOI 10.1002/1521-3765(20010702)7:13<2784::AID-CHEM2784>3.0.CO
[2] 2-A
[3] Stereodivergent allylindation of cyclopropenes. Remarkable stereodirection and acceleration by neighbouring carboxyl and hydroxyl groups
Araki, S
Nakano, H
Subburaj, K
Hirashita, T
Shibutani, K
Yamamura, H
Kawai, M
Butsugan, Y
[J]. TETRAHEDRON LETTERS, 1998, 39 (35) : 6327 - 6330
[4] Araki S., 1988, APPL ORGANOMET CHEM, V2, P475
[5] Babu G, 2000, ALDRICHIM ACTA, V33, P16
[6] Advances in indium-catalysed organic synthesis
Chauhan, KK
Frost, CG
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 2000, (18): : 3015 - 3019
[7] CINTAS P, 1995, SYNLETT, P1087
[8] Main group organometallics in synthesis
Coldham, I
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1998, (07): : 1343 - 1364
[9] GALLIUM-MEDIATED HIGHLY REGIOSELECTIVE REACTIONS OF TRIMETHYLSILYLPROPARGYL BROMIDE AND TRIMETHYLSILYLALLYL BROMIDE WITH CARBONYL-COMPOUNDS
HAN, Y
HUANG, YZ
[J]. TETRAHEDRON LETTERS, 1994, 35 (50) : 9433 - 9434
[10] Aqueous Barbier-Grignard type reaction: Scope, mechanism, and synthetic applications
Li, CJ
[J]. TETRAHEDRON, 1996, 52 (16) : 5643 - 5668

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