Subpicosecond pulse radiolysis study of geminate ion recombination in liquid benzene

被引：57

作者：

Okamoto, K ^{[1
]}

Saeki, A ^{[1
]}

Kozawa, T ^{[1
]}

Yoshida, Y ^{[1
]}

Tagawa, S ^{[1
]}

机构：

[1] Osaka Univ, Inst Sci & Ind Res, Ibaraki 5670047, Japan

来源：

CHEMISTRY LETTERS | 2003年 / 32卷 / 09期

关键词：

D O I：

10.1246/cl.2003.834

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Subpico- and picosecond pulse radiolyses were carried out to investigate geminate ion recombination in neat benzene. The fast decay of dimer radical cation corresponding to geminate ion recombination with an electron was directly observed for the first time. The characteristic lifetime and average initial distance between a thermalized electron and its parent cation were estimated to be 1.2 ps and 3.2 nm.

引用

页码：834 / 835

页数：2

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