Matrix-assisted laser-induced gas-phase aggregation of C60 oxides

被引：39

作者：

Barrow, MP

Tower, NJ

Taylor, R ^{[1
]}

Drewello, T

机构：

[1] Univ Sussex, CPES, Chem Lab, Brighton BN1 9QJ, E Sussex, England

[2] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

来源：

CHEMICAL PHYSICS LETTERS | 1998年 / 293卷 / 3-4期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1016/S0009-2614(98)00772-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Matrix-assisted laser desorption/ionisation of C-60 oxides, in conjunction with reflectron time-of-flight mass spectrometry, leads to an unprecedented gas-phase aggregation resulting in the formation of C120On-.. products. The analysis of the product distribution obtained for oxides of varying oxygen content strongly suggests that the structures of these species are closely related to ore-bridged isolated fullerene cages rather than to species featuring a fused giant fullerene core. (C) 1998 Elsevier Science B.V. All rights reserved.

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页码：302 / 308

页数：7

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