Synthesis, characterization, electrochemical, and spectroelectrochemical studies of an N-cetyl-trimethylammonium bromide/V2O5 nanocomposite

被引：22

作者：

Gimenes, MA ^{[1
]}

Profeti, LPR ^{[1
]}

Lassali, TAF ^{[1
]}

Graeff, CFO ^{[1
]}

Oliveira, HP ^{[1
]}

机构：

[1] USP, FFCLRP, Dept Fis & Matemat, Dept Quim, BR-14040901 Ribeirao Preto, Brazil

来源：

LANGMUIR | 2001年 / 17卷 / 06期

关键词：

D O I：

10.1021/la0009386

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Complex structures based on "host-guest"' systems make possible the development of new materials with promising technological applications. In this work, we synthesized a V2O5. nH(2)O/surfactant (N-cetyl-N,N,N,-trimethylammonium bromide) composite that presented an improved charge capacity and stability on electrochemical response in relation with a V2O5.1.9H(2)O matrix. CTA(+) intercalated into the V2O5 lamellar structure favors the kinetics of V-IV/V-V solid-state redox transitions. Moreover, the spectroelectrochemical behavior was verified even after several successive redox cycles.

引用

页码：1975 / 1982

页数：8

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