A Tetranuclear, Macrocyclic 3d-4f Complex Showing Single-Molecule Magnet Behavior

被引：107

作者：

Feltham, Humphrey L. C. ^{[1
,2
]}

Clerac, Rodolphe ^{[3
,4
]}

Powell, Annie K. ^{[5
]}

Brooker, Sally ^{[1
,2
]}

机构：

[1] Univ Otago, Dept Chem, Dunedin 9054, New Zealand

[2] Univ Otago, MacDiarmid Inst, Dunedin 9054, New Zealand

[3] CNRS, Ctr Rech Paul Pascal, Equipe Mat Mol Magnet, UPR 8641, F-33600 Pessac, France

[4] Univ Bordeaux, UPR 8641, F-33600 Pessac, France

[5] Karlsruher Inst Technol, Inst Anorgan Chem, D-76131 Karlsruhe, Germany

来源：

INORGANIC CHEMISTRY | 2011年 / 50卷 / 10期

关键词：

SCHIFF-BASE MACROCYCLES; TB; DY; RELAXATION; STRATEGIES; LIGANDS; HO; LN;

D O I：

10.1021/ic2003639

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[(Cu3TbIII)-Tb-II(L-Pr)(NO3)(2)(MeOH)(H2O)(2)]-(NO3)center dot 3H(2)O is a rare example of a 3d-4f single-molecule magnet prepared using a macrocyclic ligand: at low T, it exhibits frequency-dependent alternating-current susceptibility, indicative of slow relaxation of the magnetization.

引用

页码：4232 / 4234

页数：3

共 33 条

[1] SYNTHESIS, STRUCTURE, AND SPECTROSCOPIC PROPERTIES OF COPPER(II) COMPOUNDS CONTAINING NITROGEN SULFUR DONOR LIGANDS - THE CRYSTAL AND MOLECULAR-STRUCTURE OF AQUA[1,7-BIS(N-METHYLBENZIMIDAZOL-2'-YL)-2,6-DITHIAHEPTANE]COPPER(II) PERCHLORATE [J].

ADDISON, AW ;

RAO, TN ;

REEDIJK, J ;

VANRIJN, J ;

VERSCHOOR, GC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (07) :1349-1356

[2] Core/shell oligometallic template synthesis of macrocyclic hexaoxime [J].

Akine, Shigehisa ;

Sunaga, Shuichi ;

Taniguchi, Takanori ;

Miyazaki, Hayato ;

Nabeshima, Tatsuya .

INORGANIC CHEMISTRY, 2007, 46 (08) :2959-2961

[3] Cyclic and acyclic oligo(N2O2) ligands for cooperative multi-metal complexation [J].

Akine, Shigehisa ;

Nabeshima, Tatsuya .

DALTON TRANSACTIONS, 2009, (47) :10395-10408

[4] Mononuclear Lanthanide Single Molecule Magnets Based on the Polyoxometalates [Ln(W5O18)2]9- and [Ln(β2-SiW11O39)2]13- (LnIII = Tb, Dy, Ho, Er, Tm, and Yb) [J].

AlDamen, Murad A. ;

Cardona-Serra, Salvador ;

Clemente-Juan, Juan M. ;

Coronado, Eugenio ;

Gaita-Arino, Alejandro ;

Marti-Gastaldo, Carlos ;

Luis, Fernando ;

Montero, Oscar .

INORGANIC CHEMISTRY, 2009, 48 (08) :3467-3479

[5] 3d-4f Combined Chemistry: Synthetic Strategies and Magnetic Properties [J].

Andruh, Marius ;

Costes, Jean-Pierre ;

Diaz, Carmen ;

Gao, Song .

INORGANIC CHEMISTRY, 2009, 48 (08) :3342-3359

[6]

[Anonymous], 1932, NATURE, DOI DOI 10.1038/130490A0

[7] Synthesis of 3d metallic single-molecule magnets [J].

Aromi, Guillem ;

Brechin, Euan K. .

SINGLE-MOLECULE MAGNETS AND RELATED PHENOMENA, 2006, 122 :1-67

[8] Cubane variations: Syntheses, structures, and magnetic property analyses of lanthanide(III)-copper(II) architectures with controlled nuclearities [J].

Aronica, Christophe ;

Chastanet, Guillaume ;

Pilet, Guillaume ;

Le Guennic, Boris ;

Robert, Vincent ;

Wernsdorfer, Wolfgang ;

Luneau, Dominique .

INORGANIC CHEMISTRY, 2007, 46 (15) :6108-6119

[9] 3d-4f Clusters with large spin ground states and SMM behaviour [J].

Baskar, Viswanathan ;

Gopal, Kandasamy ;

Helliwell, Madeleine ;

Tuna, Floriana ;

Wernsdorfer, Wolfgang ;

Winpenny, Richard E. P. .

DALTON TRANSACTIONS, 2010, 39 (20) :4747-4750

[10] A Mixed 3d-4f 14-Metallacrown-5 Complex That Displays Slow Magnetic Relaxation through Geometric Control of Magnetoanisotropy [J].

Boron, Thaddeus T., III ;

Kampf, Jeff W. ;

Pecoraro, Vincent L. .

INORGANIC CHEMISTRY, 2010, 49 (20) :9104-9106

← 1 2 3 4 →