Air-stable n-channel organic thin-film transistors with high field-effect mobility based on N,N′-bis(heptafluorobutyl)3,4:9,10-perylene diimide

被引：142

作者：

Oh, Joon Hak

Liu, Shuhong

Bao, Zhenan

Schmidt, Ruediger

Wuerthner, Frank

机构：

[1] Stanford Univ, Dept Chem Engn, Stanford, CA 95305 USA

[2] Univ Wurzburg, Inst Organ Chem, D-97074 Wurzburg, Germany

[3] Univ Wurzburg, Rontgen Res Ctr Complex Mat Syst, D-97074 Wurzburg, Germany

来源：

APPLIED PHYSICS LETTERS | 2007年 / 91卷 / 21期

基金：

新加坡国家研究基金会;

关键词：

D O I：

10.1063/1.2803073

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

The thin-film transistor characteristics of n-channel organic semiconductor, N,N-'-bis(2,2,3,3,4,4,4-heptafluorobutyl)-perylene tetracarboxylic diimide, are described. The slip-stacked face-to-face molecular packing allows a very dense parallel arrangement of the molecules, leading to field-effect mobility as high as 0.72 cm(2) V-1 s(-1). The mobility only slightly decreased after exposure to air and remained stable for more than 50 days. Our results reveal that molecular packing effects such as close stacking of perylene diimide units and segregation effects imparted by the fluorinated side chains are crucial for the air stability. (C) 2007 American Institute of Physics.

引用

收藏

页数：3

相关论文

共 27 条

[11] ORGANIC-ON-INORGANIC SEMICONDUCTOR CONTACT BARRIER DIODES .1. THEORY WITH APPLICATIONS TO ORGANIC THIN-FILMS AND PROTOTYPE DEVICES [J].

FORREST, SR ;

KAPLAN, ML ;

SCHMIDT, PH .

JOURNAL OF APPLIED PHYSICS, 1984, 55 (06) :1492-1507

[12] Ultrathin organic films grown by organic molecular beam deposition and related techniques [J].

Forrest, SR .

CHEMICAL REVIEWS, 1997, 97 (06) :1793-1896

[13] High-mobility C60 field-effect molecular-wetting controlled transistors fabricated on substrates [J].

Itaka, Kenji ;

Yamashiro, Mitsugu ;

Yamaguchi, Jun ;

Haemori, Masamitsu ;

Yaginuma, Seiichiro ;

Matsumoto, Yuji ;

Kondo, Michio ;

Koinuma, Hideomi .

ADVANCED MATERIALS, 2006, 18 (13) :1713-+

[14] High-mobility air-stable n-type semiconductors with processing versatility:: Dicyanoperylene-3,4:9,10-bis(dicarboximides) [J].

Jones, BA ;

Ahrens, MJ ;

Yoon, MH ;

Facchetti, A ;

Marks, TJ ;

Wasielewski, MR .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (46) :6363-6366

[15] Synthetic chemistry for ultrapure, processable, and high-mobility organic transistor semiconductors [J].

Katz, HE ;

Bao, ZN ;

Gilat, SL .

ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (05) :359-369

[16] Naphthalenetetracarboxylic diimide-based n-channel transistor semiconductors: Structural variation and thiol-enhanced gold contacts [J].

Katz, HE ;

Johnson, J ;

Lovinger, AJ ;

Li, WJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (32) :7787-7792

[17] A soluble and air-stable organic semiconductor with high electron mobility [J].

Katz, HE ;

Lovinger, AJ ;

Johnson, J ;

Kloc, C ;

Siegrist, T ;

Li, W ;

Lin, YY ;

Dodabalapur, A .

NATURE, 2000, 404 (6777) :478-481

[18] A THEORETICAL-STUDY OF CRYSTALLOCHROMY - QUANTUM INTERFERENCE EFFECTS IN THE SPECTRA OF PERYLENE PIGMENTS [J].

KAZMAIER, PM ;

HOFFMANN, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (21) :9684-9691

[19] CRYSTALLOCHROMY AS A SOLID-STATE EFFECT - CORRELATION OF MOLECULAR-CONFORMATION, CRYSTAL PACKING AND COLOR IN PERYLENE-3,4-9,10-BIS(DICARBOXIMIDE) PIGMENTS [J].

KLEBE, G ;

GRASER, F ;

HADICKE, E ;

BERNDT, J .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1989, 45 :69-77

[20] Solubility- and temperature-driven thin film structures of polymeric thiophene derivatives for high performance OFET applications [J].

LeFevre, Scott W. ;

Bao, Zhenan ;

Ryu, Chang Y. ;

Siegel, Richard W. ;

Yang, Hoichang .

ORGANIC FIELD-EFFECT TRANSISTORS VI, 2007, 6658