Novel metallamacrocyclic gold(I) thiolate cluster complex:: structure and luminescence of [Au9(μ-dppm)4(μ-p-tc)6](PF6)3

被引：49

作者：

Chen, JH

Mohamed, AA

Abdou, HE

Bauer, JAK

Fackler, JP

Bruce, AE

Bruce, MRM

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

[2] Univ Maine, Dept Chem, Orono, ME 04469 USA

[3] Texas A&M Univ, Lab Mol Struct & Bonding, College Stn, TX 77842 USA

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 12期

关键词：

D O I：

10.1039/b415488f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structure of a novel metallamacrocyclic phosphine gold( I) thiolate cluster, [Au-9(mu-dppm) 4(mu-p-tc)(6)](PF6)(3), where dppm = bis( diphenylphosphine) methane and p- tc = p-thiocresolate, is reported and shows Au center dot center dot center dot Au attractions of similar to 3.0 angstrom and gold( I) atoms linked to thiolate and phosphine ligands in distorted trigonal and nearly linear geometries.

引用

页码：1575 / 1577

页数：3

共 31 条

[1]

[Anonymous], 1999, GOLD PROGR CHEM BIOC

[2]

BONDARENKO NA, 1991, SYNTHESIS-STUTTGART, P125

[3] Aurophilicity at sulfur centers. Synthesis and reactivity of the complex [S(Au(2)dppf)]; Formation of polynuclear sulfur-centered complexes. Crystal structures of [S(Au(2)dppf)]center dot 2CHCl(3), [(mu-Au(2)dppf){S(Au(2)dppf)}(2)](OTf)(2)center dot 8CHCl(3), and [S(AuPPh(2)Me)(2)(Au(2)dppf)](ClO4)(2)center dot 3CH(2)Cl(2) [J].