H/D fragment ratio in Lyman-alpha photolysis of CH2D2

被引：20

作者：

Heck, AJR ^{[1
]}

Zare, RN ^{[1
]}

Chandler, DW ^{[1
]}

机构：

[1] STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305

来源：

JOURNAL OF CHEMICAL PHYSICS | 1996年 / 104卷 / 09期

关键词：

D O I：

10.1063/1.471045

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The photofragment imaging technique is used to study the formation of H and D in the photolysis of CH2D2. From the images different reaction channels are distinguished that lead to hydrogen fragments. For the channel that leads to hydrogen atoms concomitant with methyl fragments a H/D ratio of 3.5+/-0.6 is found. (C) 1996 American Institute of Physics.

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页码：3399 / 3402

页数：4

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