Synthesis and structure of magnesium-substituted hydroxyapatite

被引:134
作者
Fadeev, IV
Shvorneva, LI
Barinov, SM
Orlovskii, VP
机构
[1] Russian Acad Sci, Inst Physicochem Problems Ceram Sci, Moscow 119361, Russia
[2] Inst Glass, Moscow 111024, Russia
[3] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia
关键词
Calcium; Phosphate; Spectroscopy; Magnesium; Inorganic Chemistry;
D O I
10.1023/A:1025509305805
中图分类号
T [工业技术];
学科分类号
08 [工学];
摘要
Magnesium-substituted calcium phosphates with the general formula Ca10-xMgx(PO4)(6)(OH)(2) (x < 1) are synthesized and characterized by IR spectroscopy and x-ray diffraction. The magnesium ion is found to destabilize the structure of hydroxyapatite: increasing the Mg content from I to 10 at. % (in terms of metals) reduces the temperature of the hydroxyapatite-whitlockite transition.
引用
收藏
页码:947 / 950
页数:4
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