Near-quantitative solid-state synthesis of carbon nanotubes from homogeneous diphenylethynecobalt and -nickel complexes

被引：54

作者：

Iyer, VS

Vollhardt, KPC ^{[1
]}

Wilhelm, R

机构：

[1] Univ Calif Berkeley, Dept Chem, Ctr New Direct Organ Syst, Berkeley, CA 94720 USA

[2] Lawrence Berkeley Natl Lab, Div Chem Sci, Berkeley, CA 94720 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 36期

关键词：

alkyne ligands; carbon; cobalt; nanotubes; nickel; solid-state synthesis;

D O I：

10.1002/anie.200352201

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Free-standing films of multiwalled carbon nanotubes (see scanning electron micrograph) encapsulating crystalline metal particles are obtained by the solid-state thermolytic conversion of commercial homogeneous organometallic systems with a defined metal-to-carbon ratio.

引用

收藏

页码：4379 / 4383

页数：5

相关论文

共 73 条

[1] Synergism of Co and Mo in the catalytic production of single-wall carbon nanotubes by decomposition of CO [J].

Alvarez, WE ;

Kitiyanan, B ;

Borgna, A ;

Resasco, DE .

CARBON, 2001, 39 (04) :547-558

[2]

[Anonymous], 2000, RUSS CHEM REV+

[3] Functionalization of carbon nanotubes by electrochemical reduction of aryl diazonium salts: A bucky paper electrode [J].

Bahr, JL ;

Yang, JP ;

Kosynkin, DV ;

Bronikowski, MJ ;

Smalley, RE ;

Tour, JM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (27) :6536-6542

[4] Carbon nanotubes - the route toward applications [J].

Baughman, RH ;

Zakhidov, AA ;

de Heer, WA .

SCIENCE, 2002, 297 (5582) :787-792

[5] Synthesis, crystal structure, and explosive decomposition of 1,2:5,6:11,12:15,16-tetrabenzo-3,7,9,13,17,19-hexadehydro[20]annulene: Formation of onion- and tube-like closed-shell carbon particles [J].

Boese, R ;

Matzger, AJ ;

Vollhardt, KPC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (08) :2052-2053

[6] Synthesis of carbon nanotubes containing metal oxides and metals of the d-block and f-block transition metals and related studies [J].

Chen, YK ;

Chu, A ;

Cook, J ;

Green, MLH ;

Harris, PJF ;

Heesom, R ;

Humphries, M ;

Sloan, J ;

Tsang, SC ;

Turner, JFC .

JOURNAL OF MATERIALS CHEMISTRY, 1997, 7 (03) :545-549

[7] Efficient formation of iron nanoparticle catalysts on silicon oxide by hydroxylamine for carbon nanotube synthesis and electronics [J].

Choi, HC ;

Kundaria, S ;

Wang, DW ;

Javey, A ;

Wang, Q ;

Rolandi, M ;

Dai, HJ .

NANO LETTERS, 2003, 3 (02) :157-161

[8] Annealing amorphous carbon nanotubes for their application in hydrogen storage [J].

Ci, LJ ;

Zhu, HW ;

Wei, BQ ;

Xu, CL ;

Wu, DH .

APPLIED SURFACE SCIENCE, 2003, 205 (1-4) :39-43

[9] Carbon nanotubes: Synthesis, integration, and properties [J].

Dai, HJ .

ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (12) :1035-1044

[10] Carbon nanotubes: opportunities and challenges [J].

Dai, HJ .

SURFACE SCIENCE, 2002, 500 (1-3) :218-241

← 1 2 3 4 5 6 7 8 →