Structure and spectroscopy of copper-dioxygen complexes

被引：1180

作者：

Mirica, LM ^{[1
]}

Ottenwaelder, X ^{[1
]}

Stack, TDP ^{[1
]}

机构：

[1] Stanford Univ, Dept Chem, Stanford, CA 94305 USA

来源：

CHEMICAL REVIEWS | 2004年 / 104卷 / 02期

关键词：

D O I：

10.1021/cr020632z

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structures and spectroscopic properties of well-characterized copper-dioxygen complexes were analyzed. The ligand attributes that create O 2-reactive Cu(I) complexes and lead to specific types of Cu/O 2 species were discussed. It was shown that prevalent formation of dimeric Cu/O 2 complexes in homogeneous solutions is consistent with the thermodynamic trends of O 2 reduction. The results show that most Cu/O 2 reactions generate a thermodynamic rather than a kinetic Cu/O 2 product.

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页码：1013 / 1045

页数：33

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