Rate constants for reactions of aliphatic carbon-centered radicals in aqueous solution

被引：215

作者：

Neta, P ^{[1
]}

Grodkowski, J ^{[1
]}

Ross, AB ^{[1
]}

机构：

[1] UNIV NOTRE DAME,RADIAT LAB,RADIAT CHEM DATA CTR,NOTRE DAME,IN 46556

来源：

JOURNAL OF PHYSICAL AND CHEMICAL REFERENCE DATA | 1996年 / 25卷 / 03期

关键词：

alkyl radicals; aminoalkyl radicals; aqueous solution; benzyl radicals; chemical kinetics; haloalkyl radicals; hydroxyalkyl radicals; photolysis; radiolysis; rate constants;

D O I：

10.1063/1.555978

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Absolute rate constants for reactions of aliphatic carbon-centered radicals in aqueous solutions have been compiled and evaluated from the literature. Rate constants are included for reactions of radicals with inorganic and organic compounds and for decay by radical-radical reactions. The radicals were generated by radiolysis, photolysis, or other techniques, and their rate constants were determined generally by kinetic spectrophotometry. The tables include data for over 2,500 reactions of 373 radicals from 740 literature references. (C) 1996 American Institute of Physics and American Chemical Society.

引用

页码：709 / 1050

页数：342

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