The high resolution spectrum of the S1←S0 transition of anisole

被引：51

作者：

Eisenhardt, CG ^{[1
]}

Pietraperzia, G

Becucci, M

机构：

[1] Free Univ Berlin, Inst Chem, D-14195 Berlin, Germany

[2] Univ Florence, LENS, I-50125 Florence, Italy

[3] Univ Florence, Dipartimento Chim, I-50121 Florence, Italy

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2001年 / 3卷 / 08期

关键词：

D O I：

10.1039/b009507i

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The high resolution electronic excitation spectrum of the band origin in the S-1<--S-0 electronic excitation of anisole has been measured in a molecular beam experiment. High accuracy upper state rotational constants have been determined from the fit of more than 400 rovibronic transitions (with a 10 MHZ standard deviation). The planarity of anisole in both the ground and the excited state has been clearly demonstrated and additional information gained about the changes in the structure with electronic excitation.

引用

页码：1407 / 1410

页数：4

共 20 条

[1] METHOXY GROUP NONPLANARITY IN OMICRON-DIMETHOXYBENZENES - SIMPLE PREDICTIVE MODELS FOR CONFORMATIONS AND ROTATIONAL BARRIERS IN ALKOXYAROMATICS [J].

ANDERSON, GM ;

KOLLMAN, PA ;

DOMELSMITH, LN ;

HOUK, KN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (09) :2344-2352

[2] THE 275-NM ABSORPTION SYSTEM OF ANISOLE [J].

BALFOUR, WJ .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1985, 109 (01) :60-72

[3] THE VIBRATIONAL-SPECTRUM OF ANISOLE [J].

BALFOUR, WJ .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1983, 39 (09) :795-800

[4] Inversion motion and S1 equilibrium geometry of 4-fluoroaniline:: Molecular beam high-resolution spectroscopy and ab initio calculations [J].

Becucci, M ;

Castellucci, E ;

López-Tocón, I ;

Pietraperzia, G ;

Salvi, PR ;

Caminati, W .

JOURNAL OF PHYSICAL CHEMISTRY A, 1999, 103 (45) :8946-8951

[5] High resolution UV spectroscopy of phenol and the hydrogen bonded phenol-water cluster [J].

Berden, G ;

Meerts, WL ;

Schmitt, M ;

Kleinermanns, K .

JOURNAL OF CHEMICAL PHYSICS, 1996, 104 (03) :972-982

[6] SPECTROSCOPIC OBSERVATION AND GEOMETRY ASSIGNMENT OF THE MINIMUM ENERGY CONFORMATIONS OF METHOXY-SUBSTITUTED BENZENES [J].

BREEN, PJ ;

BERNSTEIN, ER ;

SECOR, HV ;

SEEMAN, JI .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (06) :1958-1968

[7] ION MOLECULE REACTIONS WITHIN MOLECULAR CLUSTERS [J].

BRUTSCHY, B .

CHEMICAL REVIEWS, 1992, 92 (07) :1567-1587

[8]

GREEN JHS, 1962, SPECTROCHIM ACTA, V18, P39, DOI 10.1016/S0371-1951(62)80108-8

[9]

JANES C, 1989, THESIS FREIE U BERLI

[10] Molecular beam spectroscopy of S-1 aniline: Assignments for the 0(0)(0), 6a(0)(1), I-0(2), and 1(0)(1) rovibronic bands [J].

Kerstel, ERT ;

Becucci, M ;

Pietraperzia, G ;

Consalvo, D ;

Castellucci, E .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1996, 177 (01) :74-78

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