First of a new family of tetraamine bis(μ-thiolate)-containing macrocycles:: structure and stepwise oxidations and reductions of the dinickel(II) complex

被引：40

作者：

Brooker, S

Croucher, PD

Davidson, TC

Dunbar, GS

McQuillan, AJ

Jameson, GB

机构：

[1] Univ Otago, Dept Chem, Dunedin, New Zealand

[2] Massey Univ, Inst Fundamental Sci, Palmerston North, New Zealand

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 19期

关键词：

D O I：

10.1039/a805443f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reduction of a dinickel(II) dithiolate Schiff-base macrocyclic complex with sodium borohydride results in a 'bowl'-shaped dinickel(II) dithiolate amine macrocyclic complex which exhibits four separate one-electron redox processes.

引用

页码：2131 / 2132

页数：2

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