A direct transform for the nuclear magnetic resonance chemical shift anisotropy

被引:6
作者
de Swiet, TM [1 ]
机构
[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
[2] Univ Nottingham, Dept Chem, Nottingham NG7 2RD, England
关键词
D O I
10.1063/1.478419
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A direct transform of the NMR chemical shift anisotropy, operating on data acquired under magic angle spinning conditions, yielding rotationally invariant quantities, is potentially a source of increased resolution in solid state NMR. The mathematical basis for such a transform is discussed by exploiting an analogy with projection reconstruction. A specific example of the kind of pulse sequence required is given, and optimal sampling of the data is discussed. (C) 1999 American Institute of Physics. [S0021-9606(99)00911-3].
引用
收藏
页码:5231 / 5237
页数:7
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