Synthesis and structure of [Pt(CH=CI-CH2OCH3)2(I)2] as possible intermediate of catalytic alkynes conversion reaction into diiodosubstituted dienes

被引：21

作者：

Ananikov, V

Mitchenko, SA

Beletskaya, IP

Nefedov, SE

Eremenko, IL

机构：

[1] ND Zelinskii Organ Chem Inst, Moscow 117913, Russia

[2] AN Nesmeyanov Organoelement Cpds Inst, Moscow 117813, Russia

[3] Moscow MV Lomonosov State Univ, Moscow 119899, Russia

[4] NS Kurnakov Gen & Inorgan Chem Inst, Moscow 117907, Russia

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 1998年 / 1卷 / 11期

关键词：

platinum(IV) complexes; Pt-195; NMR; C-C coupling; iodoplatination; catalytic reaction;

D O I：

10.1016/S1387-7003(98)00102-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Direct evidence was found that catalytic alkynes conversion reaction in the system Pt(IV)-I--I-2, proceeds through a platinum(IV) sigma-vinyl complex. A synthesis, X-ray structure determination, and a multinuclear NMR study of the key-intermediate complex [Pt(CH=CI-CH2OCH3)(2)(I)(2)] as well as an expansion of the catalytic reaction are shown. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：411 / 414

页数：4

共 7 条

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