Crystal structure of the high-temperature paraelectric phase in barium titanate BaTi2O5 -: art. no. 101909

被引:30
作者
Yashima, M [1 ]
Tu, R
Goto, T
Yamane, H
机构
[1] Tokyo Inst Technol, Interdisciplinary Grad Sch Sci & Engn, Dept Mat Sci & Engn, Yokohama, Kanagawa 2268502, Japan
[2] Tohoku Univ, Mat Res Inst, Aoba Ku, Sendai, Miyagi 9808577, Japan
[3] Tohoku Univ, Interdisciplinary Res Ctr, Aoba Ku, Sendai, Miyagi 9808578, Japan
关键词
D O I
10.1063/1.2042636
中图分类号
O59 [应用物理学];
学科分类号
摘要
Crystal structure of a ferroelectric barium titanate BaTi2O5 was investigated by the Rietveld analysis of neutron powder diffraction data measured at 706 degrees C. The crystal structure of BaTi2O5 at 706 degrees C was refined assuming the centrosymmetric monoclinic A2/m space group. The crystal structures of the high-temperature A2/m and low-temperature A2 phases are similar. The displacement of atoms along the b axis is accompanied by the paraelectric A2/m to ferroelectric A2 phase transformation. The A2/m-A2 transition is not reconstructive but displacive. (c) 2005 American Institute of Physics.
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