Electrochemical charge injection into immobilized nanosized gold particle ensembles: Potential modulated transmission and reflectance spectroscopy

被引：128

作者：

Baum, T ^{[1
]}

Bethell, D ^{[1
]}

Brust, M ^{[1
]}

Schiffrin, DJ ^{[1
]}

机构：

[1] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England

来源：

LANGMUIR | 1999年 / 15卷 / 03期

关键词：

D O I：

10.1021/la980930k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Self-assembled multilayer thin films of nanometer-sized gold particles linked with organic dithiols have been prepared on glass, indium tin oxide, and gold substrates. The gold particles within these structures retain their integrity and no sintering occurs as demonstrated by their optical absorbance, ellipsometry, and potential modulated transmission and reflectance spectroscopy. The optical response to electrochemical charge injection into the outermost layer of gold particles is completely different from that of bulk gold electrodes, and it is concluded that the particles have to be regarded as discrete, immobilized quantum-dots.

引用

页码：866 / 871

页数：6

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