New photocalorimetric references for UV excitation

被引:10
作者
Murgida, DH [1 ]
ErraBalsells, R [1 ]
Bilmes, GM [1 ]
机构
[1] CONSEJO NACL INVEST CIENT & TECN,CIC,CTR INVEST OPT,RA-1900 LA PLATA,ARGENTINA
关键词
D O I
10.1016/0009-2614(95)01448-9
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A set of calorimetric references for excitation at lambda = 266 nm in acetonitrile solutions is proposed. Theophylline and several purinic compounds (purine, 6-methylpurine, 6-methoxypurine, 6-chloropurine, and 6-aminopurine) were investigated using pulsed laser optoacoustic spectroscopy with resolution times between 150 ns and 1 mu s and compared with 2-hydroxybenzophenone. At room temperature, all these compounds show no fluorescence, good stability and no photochemical processes as photodegradation or multiphotonic effects below fluences of 1000 J/m(2).
引用
收藏
页码:198 / 202
页数:5
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