Pronounced stabilisation of the ferrocenium state of ferrocenecarboxylic acid by salt bridge formation with a benzamidine

被引：17

作者：

Cooke, G ^{[1
]}

Duclairoir, FMA

Kraft, A

Rosair, G

Rotello, VM

机构：

[1] Heriot Watt Univ, Ctr Biomimet Design & Synth, Sch Engn & Phys Sci, Edinburgh EH14 4AS, Midlothian, Scotland

[2] Univ Massachusetts, Dept Chem, Amherst, MA 01002 USA

来源：

TETRAHEDRON LETTERS | 2004年 / 45卷 / 03期

基金：

美国国家科学基金会; 英国工程与自然科学研究理事会;

关键词：

ferrocenecarboxylic acid; amidine; recognition; electrochemistry;

D O I：

10.1016/j.tetlet.2003.10.218

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Salt bridge formation between ferrocenecarboxylic acid and an excess of a N,N'-diethylsubstituted benzamidine leads to a -0.27 V shift in the half-wave potential of the ferrocene moiety, corresponding to a 26 kJ mol(-1) stabilisation of the ferrocenium state. (C) 2003 Elsevier Ltd. All rights reserved.

引用

页码：557 / 560

页数：4

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