Magnetization density in a Mn high-spin (S=12) magnetic cluster

被引：9

作者：

Caneschi, A

Gatteschi, D

Sessoli, R

Schweizer, J

机构：

[1] Univ Florence, Dipartimento Chim, I-50144 Florence, Italy

[2] CEA, MDN, SPSMS, DRFMC, F-38054 Grenoble, France

来源：

PHYSICA B | 1997年 / 241卷

关键词：

polarized neutrons; spin density; magnetic cluster; molecular magnetism;

D O I：

10.1016/S0921-4526(97)00655-8

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

The magnetization density of the Mn,, cluster has been measured in a single crystal of the compound [Et3NH](2)[Mn(CH3CN)(4)(H2O)(2)]Mn10O4(biphen)(4)Br-12] by polarized neutron diffraction. The cluster has been found to be ferrimagnetic-like with all the density on the Mn atoms and no significant density on the ligands. (C) 1998 Elsevier Science B.V. All rights reserved.

引用

页码：600 / 602

页数：3

共 4 条

[1] A DECANUCLEAR MANGANESE CLUSTER WITH OXO AND HALIDE BRIDGING LIGANDS - MAGNETIC-BEHAVIOR OF AN S-GREATER-THAN-OR-EQUAL-TO-12 SYSTEM [J].