Synthesis and characterization of nitrides of iridium and palladium

被引:124
作者
Crowhurst, Jonathan C. [1 ]
Goncharov, Alexander F. [1 ,2 ,3 ]
Sadigh, B. [1 ]
Zaug, J. M. [1 ]
Aberg, D. [1 ]
Meng, Yue [4 ]
Prakapenka, Vitali B. [5 ]
机构
[1] Lawrence Livermore Natl Lab, Livermore, CA 94551 USA
[2] Carnegie Inst Sci, Geophys Lab, Washington, DC 20015 USA
[3] Carnegie Inst Sci, Geophys Lab, Washington, DC 20015 USA
[4] Argonne Natl Lab, Adv Photon Source, HPCAT, Argonne, IL 60439 USA
[5] Univ Chicago, GSECARS, Chicago, IL 60637 USA
关键词
D O I
10.1557/JMR.2008.0027
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We describe the synthesis of nitrides of iridium and palladium using the laser-heated diamond anvil cell. We have used the in situ techniques of x-ray powder diffraction and Raman scattering to characterize these compounds and have compared our experimental findings where possible to the results of first-principles theoretical calculations. We suggest that palladium nitride is isostructural with pyrite, while iridium nitride has a monoclinic symmetry and is isostructural with baddeleyite.
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页码:1 / 5
页数:5
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