Crystalline-state reaction with allosteric effect in spin-crossover, interpenetrated networks with magnetic and optical bistability

被引：332

作者：

Niel, V

Thompson, AL

Muñoz, MC

Galet, A

Goeta, ASE

Real, JA

机构：

[1] Univ Valencia, Inst Ciencia Mol, Dept Quim Inorgan, E-46100 Valencia, Spain

[2] Univ Durham, Dept Chem, Durham DH1 3LE, England

[3] Univ Politecn Valencia, Dept Fis Aplicada, E-46071 Valencia, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 32期

关键词：

allosterism; cooperative effects; crystalline-state reactions; N ligands; spin crossover;

D O I：

10.1002/anie.200351853

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A net change: A fully reversible ligand substitution involving coordination/ uncoordination of gaseous water and pyrimidine induces the repetitive allosteric transformation of three interpenetrated nets into a single three-dimensional net. The transformation does not affect the crystallinity of the sample but alters significantly the spin-crossover transition; the compound shows magnetic and chromatic bistability (see picture).

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收藏

页码：3760 / 3763

页数：4

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