Fullerene film electrodes in aqueous solutions

被引：30

作者：

Szucs, A ^{[1
]}

Loix, A ^{[1
]}

Nagy, JB ^{[1
]}

Lamberts, L ^{[1
]}

机构：

[1] FAC UNIV NOTRE DAME PAIX,LAB RMN,B-5000 NAMUR,BELGIUM

来源：

SYNTHETIC METALS | 1996年 / 77卷 / 1-3期

关键词：

fullerene; film; electrode;

D O I：

10.1016/0379-6779(96)80093-2

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Solution-cast C-60 films on gold and glassy carbon substrates can be reduced electrochemically in aqueous solutions producing an electron-conducting cation exchanger material. These films remain active even on exposure to air; their activity decreases measurably only after several hours due to some partial oxidation by oxygen. However, they can be converted irreversibly to an insulator form by electrochemical oxidation starting from about 600 mV versus SHE. Below this potential limit the reduced C-60 films can be used as electrode materials, and their specific behaviour is demonstrated with some test compounds.

引用

收藏

页码：227 / 230

页数：4

相关论文

共 12 条

[1]

Bard A.J., 1983, ELECTROCHIMIE PRINCI

[2] VOLTAMMETRY AT C-60-MODIFIED ELECTRODES [J].

COMPTON, RG ;

SPACKMAN, RA ;

RILEY, DJ ;

WELLINGTON, RG ;

EKLUND, JC ;

FISHER, AC ;

GREEN, MLH ;

DOUTHWAITE, RE ;

STEPHENS, AHH ;

TURNER, J .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1993, 344 (1-2) :235-247

[3] A C-60 MODIFIED ELECTRODE - ELECTROCHEMICAL FORMATION OF TETRA-BUTYLAMMONIUM SALTS OF C-60 ANIONS [J].

COMPTON, RG ;

SPACKMAN, RA ;

WELLINGTON, RG ;

GREEN, MLH ;

TURNER, J .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1992, 327 (1-2) :337-341

[4] ELECTRONIC-STRUCTURE, CONDUCTIVITY, AND SUPERCONDUCTIVITY OF ALKALI-METAL DOPED C-60 [J].

HADDON, RC .

ACCOUNTS OF CHEMICAL RESEARCH, 1992, 25 (03) :127-133

[5] BUCKMINSTERFULLERENE [J].

HEBARD, AF .

ANNUAL REVIEW OF MATERIALS SCIENCE, 1993, 23 :159-191

[6] ELECTROCHEMICAL REDUCTION AND OXIDATION OF C60 FILMS [J].

JEHOULET, C ;

BARD, AJ ;

WUDL, F .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (14) :5456-5457

[7] ELECTROCHEMISTRY AND LANGMUIR TROUGH STUDIES OF C-60 AND C-70 FILMS [J].

JEHOULET, C ;

OBENG, YS ;

KIM, YT ;

ZHOU, FM ;

BARD, AJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (11) :4237-4247

[8] ELECTROCHEMICAL REDUCTION OF FULLERENES IN THE PRESENCE OF O-2 AND H2O - POLYOXYGEN ADDUCTS AND FRAGMENTATION OF THE C60 FRAMEWORK [J].

KALSBECK, WA ;

THORP, HH .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1991, 314 (1-2) :363-370

[9]

LOUTFY RO, 1993, FULLERENE C60 HIST P, P307

[10] FULLERENE FILM ELECTRODES IN AQUEOUS-SOLUTIONS .1. PREPARATION AND ELECTROCHEMICAL CHARACTERIZATION [J].

SZUCS, A ;

LOIX, A ;

NAGY, JB ;

LAMBERTS, L .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1995, 397 (1-2) :191-203