Addition of arenes to ethylene and propene catalyzed by ruthenium

被引：128

作者：

Lail, M ^{[1
]}

Arrowood, BN ^{[1
]}

Gunnoe, TB ^{[1
]}

机构：

[1] N Carolina State Univ, Dept Chem, Raleigh, NC 27695 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 25期

关键词：

D O I：

10.1021/ja035076k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

TpRuII(CO)(Me)(NCMe) (Tp = hydridotris(pyrazolyl)borate) serves as a catalyst precursor for the conversion of benzene and ethylene or propene to alkylaromatic products. The reaction proceeds via the formation of the active catalyst TpRu(CO)(Ph)(NCMe) and is mildly selective for linear propylbenzene over isopropylbenzene. Copyright © 2003 American Chemical Society.

引用

页码：7506 / 7507

页数：2

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