A kinetic model to describe nanocrystal growth by the oriented attachment mechanism

被引：151

作者：

Ribeiro, C ^{[1
]}

Lee, EJH ^{[1
]}

Longo, E ^{[1
]}

Leite, ER ^{[1
]}

机构：

[1] Univ Fed Sao Carlos, Dept Quim, BR-13565905 Sao Carlos, SP, Brazil

来源：

CHEMPHYSCHEM | 2005年 / 6卷 / 04期

关键词：

coagulation; colloids; crystal growth; nanotechnology; oriented attachment;

D O I：

10.1002/cphc.200400505

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The classical model of particle coagulation on colloids is revisited to evaluate its applicability the oriented attachment of nanoparticles. The proposed model describes well the growth behavior of dispersed nanoparticles during the initial stages of nanoparticle synthesis and during growth induced by hydrothermal treatments. Moreover, a general model, which combines coarsening (i.e., Ostwold ripening) and oriented attachment effects, is proposed as an alternative to explain deviations between experimental results and existing theoretical models.

引用

页码：690 / 696

页数：7

共 48 条

[1] Biomineralization - Naturally aligned nanocrystals [J].

Alivisatos, AP .

SCIENCE, 2000, 289 (5480) :736-737

[2] Perspectives on the physical chemistry of semiconductor nanocrystals [J].

Alivisatos, AP .

JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (31) :13226-13239

[3] Aggregation-based crystal growth and microstructure development in natural iron oxyhydroxide biomineralization products [J].

Banfield, JF ;

Welch, SA ;

Zhang, HZ ;

Ebert, TT ;

Penn, RL .

SCIENCE, 2000, 289 (5480) :751-754

[4] Small-angle X-ray scattering study of the formation of colloidal silica particles from alkoxides: Primary particles or not? [J].

Boukari, H ;

Lin, JS ;

Harris, MT .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1997, 194 (02) :311-318

[5] Probing the dynamics of the silica nanostructure formation and growth by SAXS [J].

Boukari, H ;

Lin, JS ;

Harris, MT .

CHEMISTRY OF MATERIALS, 1997, 9 (11) :2376-2384

[6] Polydispersity during the formation and growth of the Stober silica particles from small-angle X-ray scattering measurements [J].

Boukari, H ;

Long, GG ;

Harris, MT .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2000, 229 (01) :129-139

[7] Structural study of self-assembled Co nanoparticles [J].

Chushkin, Y ;

Ulmeanu, M ;

Luby, S ;

Majkova, E ;

Kostic, I ;

Klang, P ;

Holy, V ;

Bochnícek, Z ;

Giersig, M ;

Hilgendorff, M ;

Metzger, TH .

JOURNAL OF APPLIED PHYSICS, 2003, 94 (12) :7743-7748

[8] EFFECT OF TEMPERATURE ON THE ENERGY AND STRUCTURE OF GRAIN-BOUNDARIES [J].

ERB, U ;

GLEITER, H .

SCRIPTA METALLURGICA, 1979, 13 (01) :61-64

[9] Nanoparticles: Strained and stiff [J].

Gilbert, B ;

Huang, F ;

Zhang, HZ ;

Waychunas, GA ;

Banfield, JF .

SCIENCE, 2004, 305 (5684) :651-654

[10] EFFECT OF SOLVENT ON THE HOMOGENEOUS PRECIPITATION OF TITANIA BY TITANIUM ETHOXIDE HYDROLYSIS [J].

HARRIS, MT ;

BYERS, CH .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 1988, 103 (01) :49-64

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