Kinetics of formation of zwitterionic complexes between 1,3,5-trinitrobenzene and diazabicyclo derivatives

被引：6

作者：

Boga, C ^{[1
]}

Forlani, L ^{[1
]}

机构：

[1] Univ Bologna, Dipartimento Chim Organ A Mangini, I-40136 Bologna, Italy

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1998年 / 10期

关键词：

D O I：

10.1039/a804013c

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The title reactions are a simple model of nucleophilic attack of tertiary nitrogen on aromatic sp(2) carbons activated by the presence of nitro groups. The formation of the zwitterionic complexes is mildly affected by solvent changes and by addition of tetraethylammonium chloride. The reactivity of 1,4-diazabicyclo[2.2.2]octane, quinuclidine and 1,8-diazabicyclo[5.4.0]undec-7-ene is compared with that of primary and secondary amines.

引用

页码：2155 / 2157

页数：3

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