Production of acrolein from glycerol over silica-supported heteropoly acids

被引：347

作者：

Tsukuda, Eriko ^{[1
]}

Sato, Satoshi ^{[1
]}

Takahashi, Ryoji ^{[1
]}

Sodesawa, Toshiaki ^{[1
]}

机构：

[1] Chiba Univ, Fac Engn, Dept Appl Chem, Chiba 2638522, Japan

来源：

CATALYSIS COMMUNICATIONS | 2007年 / 8卷 / 09期

关键词：

silica-supported heteropoly acid; glycerol; dehydration; acrolein;

D O I：

10.1016/j.catcom.2006.12.006

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Dehydration of glycerol to produce acrolein was performed over several solid acids. Supported heteropoly acids were effective as a catalyst for the dehydration of glycerol. The catalytic activity depended on the types of heteropoly acid and on the size of the mesopores in the silica support. Silicotungstic acid supported on silica with mesopores of 10 nm showed the highest catalytic activity with the acrolein selectivity of > 85 mol% at an ambient pressure and 275 degrees C. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：1349 / 1353

页数：5

共 16 条

[1] PYROLYTIC SOURCES OF HYDROCARBONS FROM BIOMASS [J].

ANTAL, MJ ;

MOK, WSL ;

ROY, JC ;

RAISSI, AT ;

ANDERSON, DGM .

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 1985, 8 (1-4) :291-303

[2] Ionic reactions and pyrolysis of glycerol as competing reaction pathways in near- and supercritical water [J].

Bühler, W ;

Dinjus, E ;

Ederer, HJ ;

Kruse, A ;

Mas, C .

JOURNAL OF SUPERCRITICAL FLUIDS, 2002, 22 (01) :37-53

[3] Glycerol hydrogenolysis on heterogeneous catalysts [J].

Chaminand, J ;

Djakovitch, L ;

Gallezot, P ;

Marion, P ;

Pinel, C ;

Rosier, C .

GREEN CHEMISTRY, 2004, 6 (08) :359-361

[4]

DOLLIMORE D, 1964, J APPL CHEM, V14, P109

[5] Synthesis of 3-buten-2-one from 4-hydroxy-2-butanone over anatase-TiO2 catalyst [J].

Ichikawa, N ;

Sato, S ;

Takahashi, R ;

Sodesawa, T .

CATALYSIS COMMUNICATIONS, 2005, 6 (01) :19-22

[6] CATALYSIS BY HETEROGENEOUS SUPPORTED HETEROPOLY ACID [J].

IZUMI, Y ;

HASEBE, R ;

URABE, K .

JOURNAL OF CATALYSIS, 1983, 84 (02) :402-409

[7] Catalysis by heteropoly acids and multicomponent polyoxometalates in liquid-phase reactions [J].

Kozhevnikov, IV .

CHEMICAL REVIEWS, 1998, 98 (01) :171-198

[8] Glycerol conversion in the aqueous solution under hydrogen over Ru/C plus an ion-exchange resin and its reaction mechanism [J].

Miyazawa, Tomohisa ;

Kusunoki, Yohei ;

Kunimori, Kimio ;

Tomishige, Keiichi .

JOURNAL OF CATALYSIS, 2006, 240 (02) :213-221

[9] Mechanisms of glycerol dehydration [J].

Nimlos, Mark R. ;

Blanksby, Stephen J. ;

Qian, Xianghong ;

Himmel, Michael E. ;

Johnson, David K. .

JOURNAL OF PHYSICAL CHEMISTRY A, 2006, 110 (18) :6145-6156

[10] Catalytic dehydration of glycerol in sub- and supercritical water: a new chemical process for acrolein production [J].

Ott, L ;

Bicker, M ;

Vogel, H .

GREEN CHEMISTRY, 2006, 8 (02) :214-220

← 1 2 →