Catalytic performance and dispersion Behavior of supported nano-amorphous alloy NiB/MCM-41 catalysts prepared by chemical reductive deposition

被引:2
作者
Lv, Z.
Xin, Q.
Guo, Z.
Song, Z.
机构
[1] Qingdao Univ Sci & Technol, Inst Chem Engn, Qingdao 266042, Peoples R China
[2] Inst Chem Ind Forest Prod, Nanjing, Peoples R China
基金
中国国家自然科学基金;
关键词
supported amorphous alloy; mesoporous molecular sieves; chemical reductive deposition; 3-(N-benzyl)-amino-4-methoxy-acetanilide;
D O I
10.1080/01932690701463100
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Supported nano-amorphous alloy NiB/MCM-41 catalysts were prepared by chemical reductive deposition. The as-prepared catalysts were characterized by XRD, SEM, TEM, EDAX, 1CP, and N-2 adsorption-desorption. The amorphous alloy structure of NiB active sites, mesoporous structure of catalysts, and higher BET area have been proved by the experiments. The catalysts have given excellent catalytic activity and selectivity in the production of 3-(N-benzyl)-amino-4methoxy- acetanilide from 3-amino-4-methoxy-acetanilide and benzaldehyde.
引用
收藏
页码:965 / 970
页数:6
相关论文
共 20 条
[1]   Pd/Pt on Ti-containing mixed oxides as dearomatization catalysts:: Physico-chemical characterization and activity [J].
Albertazzi, S ;
Barbieri, C ;
Infantes-Molina, A ;
Jiménez-López, A ;
Moreno-Tost, R ;
Rodríguez-Castellón, E ;
Vaccari, A .
CATALYSIS LETTERS, 2005, 104 (1-2) :29-37
[2]   A NEW FAMILY OF MESOPOROUS MOLECULAR-SIEVES PREPARED WITH LIQUID-CRYSTAL TEMPLATES [J].
BECK, JS ;
VARTULI, JC ;
ROTH, WJ ;
LEONOWICZ, ME ;
KRESGE, CT ;
SCHMITT, KD ;
CHU, CTW ;
OLSON, DH ;
SHEPPARD, EW ;
MCCULLEN, SB ;
HIGGINS, JB ;
SCHLENKER, JL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) :10834-10843
[3]   HYDROGENATION ACTIVITY AND SELECTIVITY OF COBALT BORIDES [J].
CHEN, YZ ;
WU, KJ .
APPLIED CATALYSIS, 1991, 78 (02) :185-197
[4]   Progress in design of new amorphous alloy catalysts [J].
Deng, JF ;
Li, HX ;
Wang, WJ .
CATALYSIS TODAY, 1999, 51 (01) :113-125
[5]  
Deng JF, 1999, CURR TOP CATAL, V2, P1
[6]   AMORPHOUS NICKEL PHOSPHORUS ALLOY DEPOSITED ON A SUPPORT AND ITS HYDROGENATION ACTIVITY [J].
JINGFA, D ;
ZHANG, XP ;
ENZE, M .
APPLIED CATALYSIS, 1988, 37 (1-2) :339-343
[7]   ORDERED MESOPOROUS MOLECULAR-SIEVES SYNTHESIZED BY A LIQUID-CRYSTAL TEMPLATE MECHANISM [J].
KRESGE, CT ;
LEONOWICZ, ME ;
ROTH, WJ ;
VARTULI, JC ;
BECK, JS .
NATURE, 1992, 359 (6397) :710-712
[8]   Crystallization deactivation of Ni-P/SiO2 amorphous catalyst and the stabilizing effect of silica support on the Ni-P amorphous structure [J].
Li, HX ;
Wang, WJ ;
Li, H ;
Deng, JF .
JOURNAL OF CATALYSIS, 2000, 194 (02) :211-221
[9]  
Ma AZ, 1999, CHINESE CHEM LETT, V10, P803
[10]   Preparation and catalytic properties of amorphous alloys in hydrogenation of sulfolene [J].
Ma, YF ;
Li, W ;
Zhang, MH ;
Zhou, Y ;
Tao, KY .
APPLIED CATALYSIS A-GENERAL, 2003, 243 (02) :215-223