The synthesis, structure and properties of diazaphospholes: Reagents and ligands for asymmetric synthesis

被引：28

作者：

De la Cruz, A ^{[1
]}

Koeller, KJ ^{[1
]}

Rath, NP ^{[1
]}

Spilling, CD ^{[1
]}

Vasconcelos, ICF ^{[1
]}

机构：

[1] Univ Missouri, Dept Chem, St Louis, MO 63121 USA

来源：

TETRAHEDRON | 1998年 / 54卷 / 35期

关键词：

D O I：

10.1016/S0040-4020(98)00502-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reaction of C-2 diamines with PCl3 and Et3N in toluene, followed by water or hydrogen sulfide, gave a series of cyclic phosphorous acid diamides (diazaphosphole oxides) and thiophosphorous acid diamides (diazaphosphole sulfides), respectively. Similarly, reaction of diamines with phenyl dichlorophosphine gave phenyl diazaphospholes. The synthesis, properties, and structure of these diazaphospholes are reported. (C) 1998 Elsevier Science Ltd. All rights reserved.

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页码：10513 / 10524

页数：12

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