Oxidative cross-coupling of N-(2′-phenylphenyl)benzenesulfonamides or benzoic and naphthoic acids with alkenes using a palladium-copper catalyst system under air

被引：333

作者：

Miura, M ^{[1
]}

Tsuda, T ^{[1
]}

Satoh, T ^{[1
]}

Pivsa-Art, S ^{[1
]}

Nomura, M ^{[1
]}

机构：

[1] Osaka Univ, Fac Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1998年 / 63卷 / 15期

关键词：

D O I：

10.1021/jo980584b

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

N-(2'-Phenylphenyl)benzenesulfonamides react with acrylate esters accompanied via cleavage of the C-H bond at their 2'-position in the presence of a catalyst system of Pd(OAc)(2) and Cu(OAc)(2) and a base under air to produce 5,6-dihydro-5-(benzenesulfonyl)phenanthridine-6-acetate derivatives in high yields. The reactions of benzoic acid with butyl acrylate and styrene can also give 3-[(butoxycarbonyl)methyl]phthalide and 3-phenylisocoumarin, respectively.

引用

页码：5211 / 5215

页数：5

共 36 条

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