Synthesis and reactions of rhenium(V) oxo-hydride complexes

被引：24

作者：

Matano, Y ^{[1
]}

Brown, SN ^{[1
]}

Northcutt, TO ^{[1
]}

Mayer, JM ^{[1
]}

机构：

[1] Univ Washington, Dept Chem, Seattle, WA 98195 USA

来源：

ORGANOMETALLICS | 1998年 / 17卷 / 14期

关键词：

D O I：

10.1021/om980184e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Tp*ReO(H)Cl, TpRe(O)H(Cl), and Tp*ReO(H)(2) have been prepared by alkoxide-for-hydride metathesis using BH3 . THF. The triflate derivative Tp*Re(O)H(OTf) inserts olefins and is oxidized by oxygen-atom transfer reagents to give HOTf and Tp*ReO3, likely by a pathway involving hydride migration to an oxo ligand (Tp* = hydrotris (3, 5-dimethyl-1-pyrazolyl)borate; triflate = OTf = OSO2CF3).

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页码：2939 / 2941

页数：3

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